Physical Changes
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Quick Quiz on Phase Changes

Physical Changes

Single Phase Changes

Diagram of phase changes [fig1phch.gif]Let’s focus on phase changes that involve materials changing from one state of matter to another. These phase changes can be brought about by heating or cooling. The terms used to identify the various changes are shown on this diagram. If you are already familiar with this terminology feel free to move on to the next topic.

Phase changes can be brought about by heating or cooling. For example if water (a liquid) is heated enough, it evaporates and becomes water vapor or steam (a gas). This kind of phase change--liquid to gas--is called evaporation or vaporization.

Water vapor can in turn be cooled to form liquid water. This kind of phase change--from gas to liquid--is referred to as condensation.

If you were to continue to cool down the water and change it from a liquid to a solid, you would have another kind of phase change that is called freezing or crystallization.

If you were to then take a solid and warm it up to change it into a liquid, that change is called melting. (It is also sometimes called fusion.)

Another change that can occur for some solids is to change directly into a gas instead of changing into a liquid, and that is called sublimation.

The reverse of this process can also occur. Some gases can be cooled down and changed directly into a solid. That process is also called crystallization, a second meaning for that word.

Multiple Phase Changes

In addition to these single phase changes, you can have a string of changes, one after another. There are three of these multiple phase changes that are very important and you should know them by name.

One is distillation, changing a liquid to a gas and back to a liquid.
distillation
LIQUID rtarrow.gif (850 bytes) GAS rtarrow.gif (850 bytes) LIQUID
The second is sublimation, which you already know means changing a solid to a gas. The term also applies to a double process in which a solid is changed to a gas and then back to a solid.
sublimation (2nd)
SOLID rtarrow.gif (850 bytes) GAS rtarrow.gif (850 bytes) SOLID
The third is recrystallization, in which a solid is changed to a liquid and then back to a solid. You will see another meaning for this term soon.
recrystallization (1st)
SOLID rtarrow.gif (850 bytes) LIQUID rtarrow.gif (850 bytes) SOLID

Dissolution and Crystallization

Another type of phase change is dissolving or dissolution. This involves a material (usually a solid) seemingly disappearing when placed into a liquid. Sugar or salt dissolving in water are examples. The condition of the sugar and salt have definitely changed--they are no longer homogeneous, opaque, white solids. But they continue to exist as sugar and salt. (This can be verified by taste, in these cases.) They have changed to a different condition or phase, but they remain the same materials. Also, the water remains water even though the taste of sugar or salt has been mixed in with it.
dissolution
SOLID rtarrow.gif (850 bytes) SOLUTION
The reverse of this process (evaporating away the water to retrieve the sugar or salt) is called crystallization (another meaning for that term).
crystallization (2nd)
SOLUTION rtarrow.gif (850 bytes) SOLID
Combining both processes (solid to solution back to solid) is a second type of recrystallization.
recrystallization (2nd)
SOLID rtarrow.gif (850 bytes) SOLUTION rtarrow.gif (850 bytes) SOLID

Recap

That gives you quite a few terms with which you may or may not be familiar. Take a moment to review them and be sure you know their meaning before continuing by taking the Quick Quiz on Phase Changes.

vaporization
condensation
distillation
crystallization
recrystallization
sublimation
dissolution